Generator of a rotation matrix
Solution 1
Your orthogonal matrix $$R(\phi,\theta)= \begin{bmatrix} \cos(\theta) &\sin(\theta) & 0 \\ \sin(\theta)\cos(\phi) & \cos(\theta)\cos(\phi) & \sin(\phi)\\ \sin(\theta)\sin(\phi) & \cos(\theta)\sin(\phi) &\cos(\phi) \end{bmatrix}$$ must have antisymmetric generators.
To find them, you must expand around the origin, $\phi=\pi, \theta=0$. To allay confusion, define $\Phi\equiv = \pi\phi$, so the origin is at $\Phi=\theta=0$. $$R(\Phi,\theta)= \begin{bmatrix} \cos(\theta) &\sin(\theta) & 0 \\  \sin(\theta)\cos(\Phi) & \cos(\theta)\cos(\Phi) & \sin(\Phi)\\ \sin(\theta)\sin(\Phi) & \cos(\theta)\sin(\Phi) &\cos(\Phi) \end{bmatrix}$$
Evaluate $R(\delta\Phi, 0)=\bigg[I+t\delta\Phi\bigg]$, so $$t= \begin{bmatrix} 0 &0 & 0 \\ 0 & 0 & 1\\ 0 &  1 &0 \end{bmatrix}.$$
Can you also evaluate $R(0,\delta \theta)$?
Note added as per comments.
The above rotation matrix R then, in the conventions of WP, is but $$ e^{\Phi L_x} e^{\theta L_z} , $$ which you might choose to compose by BCH, $$\exp (\Phi L_x \theta L_z+ \Phi \theta [L_x,L_z]/2+... ), $$ or the Gibbs finite rotation formula, etc. if you were so inclined. For orthogonal axes like yours, Gibbs' formula all but collapses: the effective axis of rotation is just parallel to $\hat z \tan (\theta/2) +\hat x \tan (\Phi/2) +\hat y \tan (\theta/2) \tan (\Phi/2)$ ! (Can you see that this is precisely the invariant vector of R?)
In any case, the limiting procedure at the origin yielding the generators from your finite rotation matrix has sacrificed information: convince yourself that several different rotation matrices may share this identical behavior at the origin, of coursethink of reversing the order of the two factors above; so you should not expect to reconstitute this specific rotation matrix from the tangent space behavior at the origin, in general. (Here you already factored your finite rotations in advance. What Lie's 3rd theorem guarantees is essentially Euler's theorem: the two component rotations will combine to a single rotation about a new axis.)
Solution 2
The parametrization you've given just isn't of the exponential form you're after.
The matrix you've written down is parametrized by the location of the $x$ axis after the rotation, which has polar angle $\theta$ and azimuthal angle $\phi$ in polar spherical coordinates drawn around the old $x$ axis. It is not a rotation by angle $\phi$ about an axis at angle $\theta$, nor is it a rotation by angle $\theta$ about any clean axis, nor is it a combination of rotations by angles $\theta$ and $\phi$. It can of course be expressed as a rotation by a certain angle about a certain axis, but that angle is neither $\theta$ nor $\phi$.
As such, there is no useful way in which finding a loworder expansion in terms of $\theta$ or $\phi$ will give you a useful generator that will recreate your matrix upon exponentiation.
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user135580
Updated on November 28, 2020Comments

user135580 over 2 years
$$T(\phi)= \begin{bmatrix} \cos(\theta) &\sin(\theta) & 0 \\ \sin(\theta)\cos(\phi) & \cos(\theta)\cos(\phi) & \sin(\phi)\\ \sin(\theta)\sin(\phi) & \cos(\theta)\sin(\phi) &\cos(\phi) \end{bmatrix}$$
Here the matrix $T$ is parametrized by $\phi$ and $\theta$=some constant angle. Can I find out the generators of this orthogonal transformation parametrized by the angle $\phi$ ? If my approach is wrong, how do I find the generators of this matrix and exponentiate it?
I have derived an infinitesimal transformation which leads to $$T(\delta\phi)=\bigg[I+t\delta\phi\bigg]$$ where $t$ is, $$t= \begin{bmatrix} 0 &0 & 0 \\ 0 & 0 & 1\\ \sin(\theta) & \cos(\theta) &0 \end{bmatrix}.$$
Here $\theta$ is some fixed angle, say $120$ degrees or $69$ degrees or anything, but it remains constant. Can I exponentiate this matrix to get $$e^{\hat{t}\phi}$$ Is it correct? Where am I going wrong if I am completely incorrect?
Edit: if $\theta$ is a fixed constant, there is no way I could get the identity element, so what if $T$ is parametrized by both $\theta$ and $\phi$ ? I will surely get the identity element. Now how do I proceed from here?

Emilio Pisanty over 3 yearsThis is wrong, starting with the zerothorder term. If you set $\phi=0$ you don't get the identity, in contrast to the identity you've written.

John Alexiou over 3 years[Formatting Note] Use
\sin
and\cos
in math expressions. It looks better, especially when things multiply the trig functions. $A sin(\omega t)$ vs. $A \sin(\omega t)$. 
user135580 over 3 years@EmilioPisanty I have edited the question as single parameter does not get me to identity element and I assume $T$ to be having two parameters

jacob1729 over 3 yearsThis is not the most general parametrisation of a rotation  you can't parametrise rotations with only two angles.

Cosmas Zachos over 3 yearsReparameterize by $\Phi\equiv \pi\phi$. The origin (identity) is then at $\theta=\Phi=0$. Proceed in your improved parameterization.

Emilio Pisanty over 3 years@Cosmas Are you saying that if I set $S(\theta,\varphi) = T(\theta, \pi\varphi)$, and $J_\theta = i\partial S/\partial \theta$, $J_\varphi= i\partial S/\partial \varphi$, then $S(\theta,\varphi) = \exp(i(J_\theta\theta + J_\varphi\varphi))$? It seems that this is the scope at which OP is thinking, and the result looks false to me.

Emilio Pisanty over 3 years@CosmasZachos The result looks false to me. I agree that, with your parametrization, the derivatives along $\theta$ and $\varphi$ are indeed $L_x$ and $L_z$, but the matrix does not seem to coincide with the full $\exp(i(L_x\theta+L_z \varphi))$ exponential. It looks to me like the two parametrizations are tangent along those two directions at the origin, but OP's expression isn't 'rectilinear' enough, in the right way, to coincide with an exponential.

Emilio Pisanty over 3 yearsIf nothing else, if you took that at fist glance, then the exponential form would imply that the rotation axis lies along the $x,z$ plane. However, this rotation axis can be obtained explicitly as $(\cot(\theta/2)\tan(\varphi/2), \tan(\varphi/2), 1)$ (unnormalized) via Mathematica's symbolic
Eigensystem
. This again indicates that the matrix isn't in exponential form. 
Cosmas Zachos over 3 years@Emilio Up to signs and conventions, $\exp (\Phi L_x) \exp (\theta L_z)$ looks fine, and of course it composes by BCH to ...

Emilio Pisanty over 3 years... a completely different expression, involving $L_y$ in the exponent, of course. I agree that the chain of exponentials is correct and useful, but I completely disagree that it's appropriate to speak of the matrix here as being 'generated' by $L_x$ and $L_z$.

Cosmas Zachos over 3 years@Emilio, indeed, I was ignoring large angles, so the finite rotations produce a $L_y$ component if that is what bothered you my first answer to your first question was glib. But it is relatively straightforward to compose two finite rotations around perpendicular axes, if, indeed, that is what the OP were asking for...


user135580 over 3 yearsThank you so much. After seeing your comments, I found one thing that this $T$ matrix seems to be a product of $R_{x}(\pi  \phi) R_{z}(\theta)$.

Emilio Pisanty over 3 years@CosmasZachos The product exponentials of angular momenta isn't the exponential of the sum of the generators, though. Saying "this matrix has antisymmetric generators" implies not just that the derivatives are antisymmetric, but that the matrix equals the exponential of the derivatives, which isn't true.

Cosmas Zachos over 3 years@Emilio The BCH composition formula will yield an expression in the Lie algebra of traceless antisymmetric matrices, which, for small angles, will be the leading term in the BCH expansion. I am not sure the axis of rotation was asked for... but the SO(3) composition law may easily produce it for perpendicular component axes.

Emilio Pisanty over 3 years@Cosmas That is ultimately up to OP to prioritise, given that the result they originally wanted is impossible, but here I find it important that we be crystal clear with what does and does not hold.

Cosmas Zachos over 3 years@Emilio... I never understood the OP asking if the logarithm of that Rotation matrix is linear in 𝜃 and Φ. We are in full agreement it isn't! If he wishes a deduction of the effective axis of rotation, it is straightforward, but also trivial by looking for that matrix's identity vector.

Emilio Pisanty over 3 years@Cosmas I don't know how to read "how do i find the generators of this matrix and exponentiate it?" other than asking for the logarithm of that matrix, but I agree, it's not particularly clear.