Ph · Physics

Can Planck’s Constant Be Derived From Maxwell’s Equations?

Published By the 9to5Science editorial team

At a glance

  1. 1. Identify the theory

    Maxwell’s equations describe classical electromagnetic fields and do not include a quantum action scale.

  2. 2. Check what they predict

    They determine electromagnetic wave propagation, including the speed of light, but not a smallest energy or action.

  3. 3. Separate related constants

    You can write h using other constants if you also supply an independent measured quantity, such as the fine-structure constant.

  4. 4. Add quantum physics

    Planck’s constant enters when the electromagnetic field or matter is quantized.

No. Maxwell’s equations describe classical electromagnetic fields; they do not determine Planck’s constant hh. They predict how electromagnetic waves propagate and interact with sources, but they do not say that light’s energy comes in discrete packets or specify the size of those packets.

Planck’s constant enters when you add quantum physics. For a photon of frequency ν\nu, quantum theory gives E=hνE=h\nu. That relation needs an action scale—hh has units of energy multiplied by time—which classical Maxwell theory does not provide.

What Maxwell’s equations do determine

In vacuum, Maxwell’s equations imply a wave equation for the electric and magnetic fields. Its wave speed is

c=1ϵ0μ0,c=\frac{1}{\sqrt{\epsilon_0\mu_0}},

where ϵ0\epsilon_0 and μ0\mu_0 are the vacuum permittivity and permeability in SI units. This is a prediction about how quickly disturbances travel. It is not a prediction about the energy of an individual light quantum.

Classical electromagnetism allows a wave’s energy to vary continuously with its amplitude. A weak wave can have less energy than a stronger one, with no smallest allowed amount specified by the equations. The theory therefore has no rule that would yield a photon energy proportional to frequency, let alone fix the proportionality constant as hh.

Why dimensional analysis does not produce h

Dimensional analysis can show which combinations of given quantities have the units of a desired quantity. It cannot create a new physical scale if the theory’s inputs do not contain enough information to set one.

The vacuum constants in Maxwell’s equations combine to give cc, a speed. They do not provide a fundamental action scale. In SI, for example, ϵ0\epsilon_0 and μ0\mu_0 alone cannot be combined into a quantity with the dimensions of action. More broadly, the classical field equations do not distinguish one value of hh from another: hh is absent from them.

A dimensional match would not, by itself, be a physical derivation anyway. Even if you introduce additional constants that can be combined into something with units of action, you still need a physical principle or measurement to show that the resulting quantity equals Planck’s constant.

How h can be written using other constants

There is a useful relation involving the fine-structure constant, α\alpha:

α=e24πϵ0ℏc,h=e22ϵ0cα,\alpha=\frac{e^2}{4\pi\epsilon_0\hbar c}, \qquad h=\frac{e^2}{2\epsilon_0 c\alpha},

where ee is the elementary charge and ℏ=h/(2π)\hbar=h/(2\pi). This lets you calculate hh if you already know ee, ϵ0\epsilon_0, cc, and α\alpha.

But this is not a derivation of hh from Maxwell’s equations. The fine-structure constant is an independent dimensionless empirical input, and the relation comes from quantum electrodynamics, not from classical Maxwell theory alone. Rewriting one constant in terms of others is different from predicting it without additional physical information.

A concrete comparison

Suppose you use Maxwell’s vacuum equations to find the speed of a wave. Given ϵ0\epsilon_0 and μ0\mu_0, you calculate c=1/ϵ0μ0c=1/\sqrt{\epsilon_0\mu_0}. The result tells you the wave speed, regardless of whether you later describe the wave classically or quantize the electromagnetic field.

To find a photon’s energy, you need the quantum relation E=hνE=h\nu. For a photon with frequency 5.0×1014 Hz5.0\times10^{14}\,\text{Hz}, using h≈6.626×10−34 J sh\approx6.626\times10^{-34}\,\text{J s} gives

E=hν=(6.626×10−34 J s)(5.0×1014 s−1)≈3.31×10−19 J.E=h\nu =(6.626\times10^{-34}\,\text{J s})(5.0\times10^{14}\,\text{s}^{-1}) \approx3.31\times10^{-19}\,\text{J}.

The frequency comes from the electromagnetic wave; the conversion from frequency to the energy of one photon uses the quantum constant. Maxwell’s equations alone supply neither that conversion rule nor the numerical value of hh.

Where Planck’s constant enters historically

Planck introduced a quantization assumption to account for the observed spectrum of thermal radiation. Classical physics could not correctly describe the spectrum at high frequencies: applying classical equipartition to electromagnetic modes leads to the ultraviolet catastrophe, an unphysical prediction of unbounded total radiation energy.

Quantization provided the missing physics. Later quantum theory made the role of hh explicit in relations such as E=hνE=h\nu and in the quantization of the electromagnetic field. Maxwell’s equations remain essential for describing classical electromagnetic fields and for the classical limit of quantum electrodynamics, but they do not generate the quantum postulate themselves.

Common mistakes

  • Confusing the speed of light with an action scale. Maxwell’s vacuum constants determine cc, which has units of speed, not units of action.
  • Treating matching units as a derivation. A combination of constants may have the units of hh without being equal to hh or explaining its value.
  • Assuming Maxwell’s equations imply photons. They describe classical fields. Photons arise when the electromagnetic field is quantized.
  • Calling a rearranged formula a prediction. A formula for hh that includes an independently measured quantity such as α\alpha uses extra empirical input; it does not derive hh from Maxwell’s equations alone.

References

  1. Introduction to Electrodynamics, David J. Griffiths
  2. Introduction to Quantum Mechanics, David J. Griffiths and Darrell F. Schroeter
  3. NIST: The NIST Reference on Constants, Units, and Uncertainty

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